Rotationally resolved photoelectron angular distributions in resonance enhanced multiphoton ionization of NO
نویسندگان
چکیده
We report calculated ionic rotational branching ratios and associated photoelectron angular distributions for ( 1 + 1') resonance enhanced multiphoton ionization ( REMPI) via the R 21 (20.5), P21 + Q11 (25.5), and P 11 (22.5) branches of theA 2 :I+(3so-) state of NO. The branching ratios are dominated by even angular momentum transfer peaks, in agreement with the ll.N +I= odd (ll.N=.N +N;) selection rule. Whereas the calculated photoelectron angular distributions are very branch dependent due to alignment, the ionic branching ratios are found to be less so. The present calculated results agree well with the experimental results of Allendorf eta/.
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